[Ru(η5-C5Me5)(Me2NCH2CH2NMe2)]+, a Stable 16-Electron Complex. Reaction with Dioxygen and Formation of a Monomeric Hydroxoruthenium Tetramethylfulvene Complex-Reference-Cited by-同舟云学术

[Ru(η5-C5Me5)(Me2NCH2CH2NMe2)]+, a Stable 16-Electron Complex. Reaction with Dioxygen and Formation of a Monomeric Hydroxoruthenium Tetramethylfulvene Complex

Published:1997-12-01 Issue:26 Volume:16 Page:5601-5603
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Gemel Christian¹,Mereiter Kurt¹,Schmid Roland¹,Kirchner Karl¹

Affiliation:

1. Institute of Inorganic Chemistry and Institute of Mineralogy, Crystallography, and Structural Chemistry, Technical University of Vienna, Getreidemarkt 9, A-1060 Vienna, Austria

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9706774

Reference17 articles.

1. .pi.-Stabilized, yet Reactive, Half-Sandwich Cp*Ru(PR3)X Compounds: Synthesis, Structure, and Bonding

2. Irreversible binding of dioxygen and other gases to a half-sandwich ruthenium(II) complex: X-ray structure of [Ru(η2-O2)(η5-C5Me5)(Ph2PCH2CH2PPh2)]PF6

3. Reversible and Irreversible Coordination of Small Molecules to the Cp*Ru Fragment by a Facile Cleavage of the Ruthenium-Oxygen Bond of .eta.2P-O-Chelated (1,3-Dioxan-2-ylmethyl)diphenylphosphine

4. Synthesis of new half-sandwich ruthenium complexes containing 1,2-bis(diisopropylphosphino)ethane (dippe); crystal structures of [Ru(C5Me5)Cl(dippe)] and [Ru(C5Me5)(O2)(dippe)][BPh4]

5. Synthesis and Reactivity of RuCp*(κ2(P,N)-Ph2PCH2CH2NMe2)Cl. Chelate-Assisted Methyl C−H Activation and Formation of the Novel Complex [RuCp*(κ3(P,N,C)- Ph2PCH2CH2N(CH2)Me)Cl]BPh4

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