Dimerization of β-Diketiminato Calcium Complexes through Dihapto-Acetylide Ligation
Author:
Affiliation:
1. Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London, SW7 2AZ, U.K., and The Chemistry Laboratory, University of Sussex, Falmer, Brighton, East Sussex, BN1 9QJ, U.K.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0490334
Reference37 articles.
1. Formation and reactions of mono- and bis(peralkylcyclopentadienyl) complexes of calcium and barium. The x-ray crystal structure of [cyclic][(Me4EtC5)Ca(.mu.-NSiMe2CH2CH2SiMe2)]2
2. Lipophilic strontium and calcium alkyls, amides and phenoxides; X-ray structures of the crystalline square-planar [{trans-Sr(NR′2)2(µ-1,4-dioxane)}∞] and tetrahedral [CaR2(1,4-dioxane)2]; R′= SiMe3, R = CH(SiMe3)2]
3. The first structurally characterised solvent-free ς-bonded diorganocalcium, Ca[C(SiMe3)3]2
4. Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry
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