Thermal Reactions of anti- and syn-Dispiro[5.0.5.2]tetradeca-1,8-dienes: Stereomutation and Fragmentation to 3-Methylenecyclohexenes. Entropy-Dictated Product Ratios from Diradical Intermediates?-Reference-Cited by-同舟云学术

Thermal Reactions of anti- and syn-Dispiro[5.0.5.2]tetradeca-1,8-dienes: Stereomutation and Fragmentation to 3-Methylenecyclohexenes. Entropy-Dictated Product Ratios from Diradical Intermediates?

Published:2001-05-16 Issue:23 Volume:123 Page:5532-5541
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Doering W. von E.¹,Ekmanis Juris L.¹,Belfield Kevin D.¹,Klärner F.-G.¹,Krawczyk Bernd¹

Affiliation:

1. Contribution from the Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138-2902, and the Institut für Organische Chemie, Universität GH Essen, D-45117 Germany

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja004128s

Reference62 articles.

1. Is tetramethylene an intermediate?

2. Dynamics of singlet biradicals. Application of ab initio variational transition state theory to the fragmentation of tetramethylene

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