Synthesis, Characterization, and Reactivity of Niobium and Tantalum Complexes Bearing Metal−Nitrogen Bonds. X-ray Molecular Structure of [Nb(C5H4SiMe3){NH(CH2)2-η-NH2}Cl3] and the Novel Tetranuclear Niobium Oxo Derivative [{Nb(C5H4SiMe3)Cl(μ2-O)}4(Cl)2(μ3-O)]-Reference-Cited by-同舟云学术

Synthesis, Characterization, and Reactivity of Niobium and Tantalum Complexes Bearing Metal−Nitrogen Bonds. X-ray Molecular Structure of [Nb(C5H4SiMe3){NH(CH2)2-η-NH2}Cl3] and the Novel Tetranuclear Niobium Oxo Derivative [{Nb(C5H4SiMe3)Cl(μ2-O)}4(Cl)2(μ3-O)]

Published:2007-07-13 Issue:17 Volume:26 Page:4243-4251
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Maestre M. Carmen¹,Paniagua Cristina¹,Herdtweck Eberhardt¹,Mosquera Marta E. G.¹,Jiménez Gerardo¹,Cuenca Tomás¹

Affiliation:

1. Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Spain, and Department Chemie, Lehrstuhl für Anorganische Chemie, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching bei München, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om7002927

Reference79 articles.

1. Insertion of CO and CNR into Tantalum−Methyl Bonds of Imido(pentamethylcyclopentadienyl)tantalum Complexes. X-ray Crystal Structures of [TaCp*(NR)Me{η2-C(Me)NR}] and [TaCp*Cl(O){η2-C(Me)NR}] (R = 2,6-Me2C6H3)

2. Oxo and imido/imido exchange and C–H activation reactions based on pentamethylcylopentadienyl imido tantalum complexes

3. Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions

4. Reactions and Applications of Titanium Imido Complexes

5. The role of bismuth in the SOHIO process

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