Insertion of CO and CNR into Tantalum−Methyl Bonds of Imido(pentamethylcyclopentadienyl)tantalum Complexes. X-ray Crystal Structures of [TaCp*(NR)Me{η2-C(Me)NR}] and [TaCp*Cl(O){η2-C(Me)NR}] (R = 2,6-Me2C6H3)-Reference-Cited by-同舟云学术

Insertion of CO and CNR into Tantalum−Methyl Bonds of Imido(pentamethylcyclopentadienyl)tantalum Complexes. X-ray Crystal Structures of [TaCp*(NR)Me{η2-C(Me)NR}] and [TaCp*Cl(O){η2-C(Me)NR}] (R = 2,6-Me2C6H3)

Published:1996-08-06 Issue:16 Volume:15 Page:3579-3587
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Gómez Manuel¹,Gómez-Sal Pilar¹,Jiménez Gerardo¹,Martín Avelino¹,Royo Pascual¹,Sánchez-Nieves Javier¹

Affiliation:

1. Departamento de Química Inorgánica, Universidad de Alcalá de Henares, Campus Universitario, E-28871 Alcalá de Henares, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9602015

Reference48 articles.

1. Synthetic and Mechanistic Aspects of Inorganic Insertion Reactions. Insertion of Carbon Monoxide

2. Reaction of carbon monoxide with (.eta.5-pentamethylcyclopentadienyl)tetramethyltantalum. Intramolecular reductive coupling of carbon monoxide via an ".eta.2-acetone" intermediate

3. Carbon monoxide insertion into transition metal-carbon sigma-bonds

4. Transition Metal-lsocyanide Complexes

5. Dialkylbis[bis(trimethylsilyl)amido]zirconium(IV) and -hafnium(IV). Preparation and reaction with carbon dioxide and tert-butylisocyanide

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