Reaction of the Cationic Cluster [Os3(μ-H)(CO)10(μ-η1:η2-CCCMe2)]BF4 with Triphenylphosphine. Formation and Transformations of the σ-Acetylide Cluster [Os3(μ-H)(CO)10(PPh3)(σ-C⋮CCMe2PPh3)]BF4 and Two Isomeric Clusters [Os3(μ-H)(CO)9(PPh3)(μ-σ:η2-C⋮CCMe2PPh3)]BF4
Author:
Affiliation:
1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Vavilova 28, 119991 Moscow, Russian Federation
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om010142h
Reference34 articles.
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3. Reactivity patterns for multisite-bound acetylides. Nucleophilic attack at the .alpha.-carbon in .mu.2-.eta.2-acetylides. Bridging 2-amino-1-metallaphenethylidene complexes via addition of primary amines to M2(CO)6(.mu.2-.eta.2-C.tplbond.CPh)(.mu.-PPh2) (M = Fe, Ru, Os)
4. Nucleophilic addition at the bridging ethynyl ligand in [Os3H(µ-3-CCH)(CO)9] and hydrolytic cleavage of the carbon–carbon triple bond
5. (Aminoethyne)triosmium clusters
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