Alkylation of Deltahedral Zintl Clusters: Synthesis of [R−Ge9−Ge9−R]4- (R = tBu, sBu, nBu, tAm) and Structure of [tBu−Ge9−Ge9−tBu]4-
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic0623314
Reference37 articles.
1. Chemistry of Deltahedral Zintl Ions
2. [Ph2Bi−(Ge9)−BiPh2]2-: A Deltahedral Zintl Ion Functionalized by Exo-Bonded Ligands
3. Derivatization of Deltahedral Zintl Ions by Nucleophilic Addition: [Ph−Ge9−SbPh2]2- and [Ph2Sb−Ge9−Ge9−SbPh2]4-
4. Rationally Functionalized Deltahedral Zintl Ions: Synthesis and Characterization of[Ge9ER3]3−,[R3EGe9ER3]2−, and[R3EGe9Ge9ER3]4− (E=Ge, Sn; R=Me, Ph)
5. Organozinc Derivatives of Deltahedral Zintl Ions: Synthesis and Characterization of closo-[E9Zn(C6H5)]3- (E = Si, Ge, Sn, Pb)
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