Oxidative Addition of H−SiR3 to Di- and Triruthenium Carbonyl Complexes Bearing a Bridging Azulene Ligand:  Isolation of New Silylruthenium Complexes and Catalytic Hydrosilylation of Ketones

Author:

Matsubara Kouki1,Ryu Kazuhiro1,Maki Tomoyuki1,Iura Takafumi1,Nagashima Hideo1

Affiliation:

1. Institute of Advanced Material Study, Interdisciplinary Graduate School of Engineering Sciences, and CREST, Japan Science and Technology Corporation (JST), Kyushu University, Kasuga, Fukuoka 816-8580, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference54 articles.

1. For reviews for catalytic hydrosilylation reactions:  (a)ComprehensiveHandbook on Hydrosilylation; Marciniec, B. Ed.; Pergamon Press:  Oxford, 1992. (b) Marciniec, B. InApplied Homogeneous Catalysis withOrganometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH:  Weinheim, 1996; Vol. 1, Chapter 2.6, p 487. (c) Ojima, I. InThe Chemistry ofOrganosilicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley:  New York, 1989; p 1479. (d) Brook, M. A. InSilicon in Organic, Organometallic, andPolymer Chemistry; Wiley:  New York, 2000; Chapter 12.8, p 401. (e) Spier, J. L.Adv. Organomet. Chem.1978,17, 407.

2. Homogeneous Catalysis. IV. Some Reactions of Silicon Hydrides in the Presence of Cobalt Carbonyls

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