Cleavage of Si–H and Si–C Bonds by Metal–Ligand Cooperation: Formation of Silyl Anion and Silylene Equivalents from Tertiary Silanes-Reference-Cited by-同舟云学术

Cleavage of Si–H and Si–C Bonds by Metal–Ligand Cooperation: Formation of Silyl Anion and Silylene Equivalents from Tertiary Silanes

Published:2022-02-21 Issue:5 Volume:41 Page:659-665
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Higashi Takuya¹^ORCID,Kusumoto Shuhei¹²^ORCID,Nozaki Kyoko¹^ORCID

Affiliation:

1. Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

2. Japan Science and Technology Agency (JST), Precursory Research for Embryonic Science and Technology (PRESTO), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

Funder

Precursory Research for Embryonic Science and Technology

Japan Society for the Promotion of Science

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.2c00037

Reference50 articles.

1. Hydrosilylation

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3. Harrod, J. F., Chalk, A. J., Wender, I., Pino, P., Eds. Organic Synthesis via Metal Carbonyls; Wiley: New York, 1977; Vol. 2, p 673.

4. Synthetic Development and Chemical Reactivity of Transition-Metal Silylene Complexes

5. Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism

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