A Four-Electron π-Alkyne Complex as Precursor for Allenylidene Derivatives: Preparation, Structure, and Reactivity of [Os(η5-C5H5)(CCCPh2)L(PiPr3)]PF6 (L = CO, PHPh2)-Reference-Cited by-同舟云学术

A Four-Electron π-Alkyne Complex as Precursor for Allenylidene Derivatives: Preparation, Structure, and Reactivity of [Os(η5-C5H5)(CCCPh2)L(PiPr3)]PF6 (L = CO, PHPh2)

Published:2004-10-20 Issue:24 Volume:23 Page:5787-5798
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Asensio Adriana¹,Buil María L.¹,Esteruelas Miguel A.¹,Oñate Enrique¹

Affiliation:

1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om049479k

Reference56 articles.

1. Transition Metal Complexes Containing Allenylidene, Cumulenylidene, and Related Ligands

2. Recent Developments in the Reactivity of Allenylidene and Cumulenylidene Complexes

3. Electrophilic Half-Sandwich (Carbene)metal (Metal = Fe, Ru, Os) Complexes: Recent Developments in Synthesis and Applications

4. Highly Active Catalysts in Alkene Metathesis: First Observed Transformation of Allenylidene into Indenylidene via Alkenylcarbyne—Ruthenium Species

5. Synthesis of indenyl-ruthenium(II) σ-alkynyl complexes via nucleophilic addition of (1R)-(+)- and (1S)-(−)-camphor enolates on the allenylidene group of [Ru(CCCPh2)(η5-C9H7)(PPh3)2][PF6]: Efficient synthesis of novel optically pure vinylidene derivatives

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