Aromatic chloroosmacyclopentatrienes-Reference-Cited by-同舟云学术

Aromatic chloroosmacyclopentatrienes

Published:2022-10-28 Issue:3 Volume:10 Page:
ISSN:2095-5138
Container-title:National Science Review
language:en
Short-container-title:

Author:

Chu Zhenwei¹,He Guomei¹,Shi Chuan²,Hua Yuhui³,Huang Yaxi¹,Chen Jiangxi¹^ORCID,Xie Hujun⁴,Jia Guochen²

Affiliation:

1. Department of Materials Science and Engineering, College of Materials, Xiamen University , Xiamen 361005, China

2. Department of Chemistry, The Hong Kong University of Science and Technology , Hong Kong , China

3. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China

4. Department of Applied Chemistry, Zhejiang Gongshang University , Hangzhou 310018, China

Abstract

ABSTRACT Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed metallaaromatic with a chlorine atom in its framework. Single-crystal X-ray diffraction studies show that these planar chloroosmacyclopentatrienes possess a very short Os–ClC distance suggesting M=ClC bond character.

Funder

National Natural Science Foundation of China

Publisher

Oxford University Press (OUP)

Subject

Multidisciplinary

Link

https://academic.oup.com/nsr/advance-article-pdf/doi/10.1093/nsr/nwac237/46681387/nwac237.pdf

Reference50 articles.

1. Coordination chemistry of halocarbons;Kulawiec;Coord Chem Rev,1990

2. Syntheses and structures of alkyl and aryl halide complexes of the type [(PiPr3)2PtH(η1-XR)]BArf and analogues with Et2O, THF, and H2 ligands. Halide-to-metal π bonding in halocarbon complexes;Butts;J Am Chem Soc,1996

3. Stable bromonium and chloronium salts;Sandin;J Am Chem Soc,1952