Triple Shifts and Thioether Assistance in Rearrangements Associated with an Unusual Biomethylation of the Sterol Side Chain
Author:
Affiliation:
1. Department of Chemistry, University of California−Davis, 1 Shields Avenue, Davis, California 95616, United States
2. Department of Chemistry, State University of New York-ESF, 1 Forestry Drive, Syracuse, New York 13210, United States
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo3024208
Reference56 articles.
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4. Biosynthetic studies of marine lipids. 4. Mechanism of side chain alkylation in E-24-propylidenecholesterol by a Chrysophyte alga
5. Synthesis of (24R,28R)- and (24S,28S)-24,28-methylene-5-stigmasten-3.beta.-ol and biosynthetic implications of cyclopropyl cleavage to 24-substituted cholesterols
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