Redox Potential and C−H Bond Cleaving Properties of a Nonheme FeIV═O Complex in Aqueous Solution
Author:
Affiliation:
1. Department of Chemistry, and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, Minnesota 55455
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja909923w
Reference39 articles.
1. EXAFS Spectroscopic Evidence for an Fe═O Unit in the Fe(IV) Intermediate Observed during Oxygen Activation by Taurine:α-Ketoglutarate Dioxygenase
2. Direct spectroscopic detection of a C-H-cleaving high-spin Fe(IV) complex in a prolyl-4-hydroxylase
3. Non-Heme Fe(IV)–Oxo Intermediates
4. Spectroscopic Evidence for a High-Spin Br-Fe(IV)-Oxo Intermediate in the α-Ketoglutarate-Dependent Halogenase CytC3 from Streptomyces
5. High-valent nonheme iron-oxo species in biomimetic oxidations
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