Elucidating the role of the <i>o</i>-methoxy group in the lower rim appended salicylideneamine substituents of calix[4]arene ligands on the molecular and electronic structures of dinuclear Fe(<scp>iii</scp>)-based diamond-core complexes-Reference-Cited by-同舟云学术

Elucidating the role of the o-methoxy group in the lower rim appended salicylideneamine substituents of calix[4]arene ligands on the molecular and electronic structures of dinuclear Fe(iii)-based diamond-core complexes

Published:2024 Issue:29 Volume:26 Page:3973-3988
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Strelnikova Iuliia V.¹²^ORCID,Shutilov Ilya D.¹,Ovsyannikov Alexander S.¹^ORCID,Islamov Daut R.³,Pyataev Andrew V.²,Gerasimova Tatiana P.¹^ORCID,Khamatgalimov Ayrat R.¹^ORCID,Khrizanforov Mikhail N.¹²^ORCID,Gubaidullin Aidar T.¹^ORCID,Burilov Vladimir A.²^ORCID,Solovieva Svetlana E.¹,Antipin Igor S.²^ORCID

Affiliation:

1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzova 8 str, Kazan 420088, Russian Federation

2. Kazan Federal University, Kremlevskaya 18 str, Kazan 420008, Russian Federation

3. Laboratory for Structural Analysis of Biomacromolecules, Kazan Scientific Center of Russian Academy of Sciences, Lobachevskogo 2 str, Kazan 420008, Russian Federation

Abstract

Two new Fe(iii)-based dinuclear diamond-core clusters were prepared and characterized. Their molecular structure and band gap are regulated by the o-methoxy groups anchored at the salicylideneamine coordination sites of the ligand.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D4CE00347K

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