Significant O–H Bond Weakening in CpMn(CO)2(CH3OH): Evidence for the Generation of the CpMn(CO)2(CH3O) Radical upon H Atom Abstraction by O2-Reference-Cited by-同舟云学术

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Significant O–H Bond Weakening in CpMn(CO)2(CH3OH): Evidence for the Generation of the CpMn(CO)2(CH3O) Radical upon H Atom Abstraction by O2

Published:2013-07-23 Issue:15 Volume:32 Page:4359-4365
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Kee Jun Wei¹,Chwee Tsz Sian²,Tan Xiang Yeow¹,Webster Richard D.³,Fan Wai Yip¹

Affiliation:

1. Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543

2. Institute of High Performance Computing, Agency for Science, Research and Technology (A*STAR), 1 Fusionopolis Way, Singapore 138632

3. Division of Chemistry & Biological Chemistry, Nanyang Technological University SPMS-04-01, 21 Nanyang Avenue, SPMS-CBC-06-07, Singapore 637371

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om400504c

Reference46 articles.

1. Photochemistry of metal carbonyls

2. Seventeen-electron metal-centered radicals

3. Detection of Transient Organometallic Species by Fast Time-Resolved IR Spectroscopy

4. Nanosecond time-resolved infrared spectroscopy: a comparative view of spectrometers and their applications in organometallic chemistry

5. Flash photolysis with infrared detection. The photochemistry and secondary thermal reactions of M(CO)6 [M = Cr, Mo, and W]

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1. Half-sandwich manganese complexes Cp(CO)2Mn(NHC) as redox-active organometallic fragments;Dalton Transactions;2021

2. Cyclic and Non-Cyclic Pi Complexes of Manganese;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2021

3. CO-Photolysis-Induced H-Atom Transfer from MnIO–H Bonds;Inorganic Chemistry;2019-03-13

4. Reaction of Methylcyclopentadienyl Manganese Tricarbonyl on Silicon Oxide Surfaces: Implications for Thin Film Atomic Layer Depositions;Organometallics;2014-09-09

5. A persistent manganese carbonyl radical with infrared absorption and fluorescence modality;Journal of Organometallic Chemistry;2014-06

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