A Kinetic Study on Nucleophilic Displacement Reactions of Aryl Benzenesulfonates with Potassium Ethoxide: Role of K+ Ion and Reaction Mechanism Deduced from Analyses of LFERs and Activation Parameters-Reference-Cited by-同舟云学术

A Kinetic Study on Nucleophilic Displacement Reactions of Aryl Benzenesulfonates with Potassium Ethoxide: Role of K+ Ion and Reaction Mechanism Deduced from Analyses of LFERs and Activation Parameters

Published:2012-12-20 Issue:2 Volume:78 Page:490-497
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Um Ik-Hwan¹,Kang Ji-Sun¹,Shin Young-Hee¹,Buncel Erwin²

Affiliation:

1. Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea

2. Department of Chemistry, Queen’s University, Kingston, Ontario K7L 3N6, Canada

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo302373y

Reference73 articles.

1. Solvent induced cooperativity of Zn(ii) complexes cleaving a phosphatediester RNA analog in methanol

2. Cu(II)-Promoted Methanolysis of N,N-Dipicolylacetamide. Multistep Activation by Decoupling of >N̈–C═O Resonance via Cu(II)–N Binding, Delivery of the Cu(II):(−OCH3) Nucleophile, and Metal Ion Assistance of the Departure of the Leaving Group

3. Comparison of Cu(II)-Promoted Leaving Group Stabilization of the Cleavage of a Homologous Set of Phosphate Mono-, Di-, and Triesters in Water, Methanol, and Ethanol

4. A Study of the Kinetics of La3+-Promoted Methanolysis ofS-Aryl Methylphosphonothioates: Possible Methodology for Decontamination of EA 2192, the Toxic Byproduct of VX Hydrolysis

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