Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer
Author:
Affiliation:
1. Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic100469x
Reference12 articles.
1. Electrochemical concerted proton and electron transfers. Potential-dependent rate constant, reorganization factors, proton tunneling and isotope effects
2. Mediator-assisted water oxidation by the ruthenium “blue dimer” cis,cis-[(bpy)2(H2O)RuORu(OH2)(bpy)2]4+
3. Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II
4. aUtilization of a previously published synthetic procedure for the surface catalyst, [Ru(4,4′-((HO2)2P(O)CH2)2bpy)2(bpy)]Cl2,(4b)gave CV surface enhancements but with qualitatively different waveforms (Figures SI12−SI14 in theSI). As will be discussed in a later manuscript, these preparations gave greater than monolayer coverages and the products appear to be oligomeric in nature.
5. Potentiostatic Modulation of the Lifetime of Light-Induced Charge Separation in a Heterosupermolecule
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