Conversion of Core Oxos to Water Molecules by 4e-/4H+ Reductive Dehydration of the Mn4O26+ Core in the Manganese−Oxo Cubane Complex Mn4O4(Ph2PO2)6: A Partial Model for Photosynthetic Water Binding and Activation
Author:
Affiliation:
1. Chemistry Department, Hoyt Laboratory, Princeton University, Princeton, New Jersey 08544
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9911421
Reference49 articles.
1. Calcium Induces Binding and Formation of a Spin-Coupled Dimanganese(II,II) Center in the Apo-Water Oxidation Complex of Photosystem II as Precursor to the Functional Tetra-Mn/Ca Cluster
2. Quantitative Kinetic Model for Photoassembly of the Photosynthetic Water Oxidase from Its Inorganic Constituents: Requirements for Manganese and Calcium in the Kinetically Resolved Steps,
3. Manganese Cluster in Photosynthesis: Where Plants Oxidize Water to Dioxygen
4. Where Plants Make Oxygen: a Structural Model for the Photosynthetic Oxygen-Evolving Manganese Cluster
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