Electronic Effects in the Reactions of Olefin-Coordinated Gold Carbene Complexes
Author:
Affiliation:
1. Laboratorium für Organische Chemie, ETH Zürich, Wolfgang-Pauli-Strasse 10, CH-8093 Zürich, Switzerland
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om800795v
Reference24 articles.
1. Gas-Phase Synthesis and Reactivity of a Gold Carbene Complex
2. One may argue that observation of the cyclopropanation channel could also be achieved by sequential loss of the olefin and carbene moieties. However, quantitative CID determination for this path agrees well with DFT calculations, thus confirming our assignment: Unpublished results.
3. Cationic Gold(I) Complexes: Highly Alkynophilic Catalysts for theexo- andendo-Cyclization of Enynes
4. Gold(I)-Catalyzed Intermolecular Cyclopropanation of Enynes with Alkenes: Trapping of Two Different Gold Carbenes
5. A Gold Catalyst for Carbene-Transfer Reactions from Ethyl Diazoacetate
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