Asymmetric Deprotonation using s-BuLi or i-PrLi and Chiral Diamines in THF: The Diamine Matters
Author:
Affiliation:
1. Department of Chemistry, University of York, Heslington, York YO10 5DD, U.K., and Department of Chemistry, University of Gothenburg, SE-412 96 Göteborg, Sweden
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja107672h
Reference39 articles.
1. Generation of Enantiomerically Enriched Lithium Indenides by Means of(–)-Sparteine: Structure, Stereoselective Substitution, and Solvent Effects
2. Asymmetric Deprotonation by BuLi/(−)-Sparteine: Convenient and Highly Enantioselective Syntheses of (S)-2-Aryl-Boc-Pyrrolidines
3. (−)-Sparteine-Mediated α-Lithiation of N-Boc-N-(p-methoxyphenyl)benzylamine: Enantioselective Syntheses of (S) and (R) Mono- and Disubstituted N-Boc-benzylamines
4. Asymmetric Deprotonations: Lithiation of N-(tert-Butoxycarbonyl)indoline with sec-Butyllithium/(−)-Sparteine
5. Chiral base promoted enantioselective rearrangement of organophosphorus epoxides
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