Selective Reductions. 59. Effective Intramolecular Asymmetric Reductions of α-, β-, and γ-Keto Acids with Diisopinocampheylborane and Intermolecular Asymmetric Reductions of the Corresponding Esters with B-Chlorodiisopinocampheylborane-Reference-Cited by-同舟云学术

Selective Reductions. 59. Effective Intramolecular Asymmetric Reductions of α-, β-, and γ-Keto Acids with Diisopinocampheylborane and Intermolecular Asymmetric Reductions of the Corresponding Esters with B-Chlorodiisopinocampheylborane

Published:2002-06-29 Issue:15 Volume:67 Page:5315-5319
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Ramachandran P. Veeraraghavan¹,Pitre Sangeeta¹,Brown Herbert C.¹

Affiliation:

1. Herbert C. Brown Center for Borane Research, Purdue University, West Lafayette, Indiana 47907-1393

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo025594y

Reference24 articles.

1. Chiral synthesis via organoboranes. 14. Selective reductions. 41. Diisopinocampheylchloroborane, an exceptionally efficient chiral reducing agent

2. Chiral synthesis via organoboranes. 18. Selective reductions. 43. Diisopinocampheylchloroborane as an excellent chiral reducing reagent for the synthesis of halo alcohols of high enantiomeric purity. A highly enantioselective synthesis of both optical isomers of Tomoxetine, Fluoxetine, and Nisoxetine

3. Selective reductions. 23. Asymmetric reduction of representative ketones with diisopinocampheylborane of high optical purity

4. A remarkable inversion in configuration of the product alcohols from theasymmetric reduction of ortho-hydroxyacetophenones with B-chlorodiisopinocampheylborane

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