Synthetic Aspects of (C5H4SiMe3)3Ln Rare-Earth Chemistry: Formation of (C5H4SiMe3)3Lu via [(C5H4SiMe3)2Ln]+ Metallocene Precursors
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om400116d
Reference56 articles.
1. Nonclassical Organolanthanoid Metal Chemistry: [K([18]-crown-6)(η2-PhMe)2]X (X = [(LnCpt3)2(μ-H)], [(LnCp‘ ‘2)2(μ-η6:η6-PhMe)]) from [LnCpx3], K, and [18]-crown-6 in Toluene (Ln = La, Ce; Cpt = η5-C5H4SiMe2But; Cp‘ ‘ = η5-C5H3(SiMe3)2-1,3)
2. Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State
3. Expanding Rare-Earth Oxidation State Chemistry to Molecular Complexes of Holmium(II) and Erbium(II)
4. Synthesis of a Crystalline Molecular Complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y]
5. Structural studies on cyclopentadienyl compounds of trivalent cerium: tetrameric (MeC5H4)3Ce and monomeric (Me3SiC5H4)3Ce and [(Me3Si)2C5H3]3Ce and their coordination chemistry
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