Dynamic Behavior of the Diphosphine Ligand in H4Ru4(CO)10(dppe) Revisited: Kinetic Data Supporting a Nondissociative Isomerization of the Dppe Ligand
Author:
Affiliation:
1. Department of Chemistry, University of North Texas, Denton, Texas 76203
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic060463r
Reference19 articles.
1. Synthesis, crystal structure, and dynamic behavior of tetra-.mu.-hydrido-.mu.-[1,2-bis(diphenylphosphino)ethane]-decacarbonyltetraruthenium, an isomer of (.mu.-H)4Ru4(CO)10(diphos) with a bridging diphos ligand
2. Synthesis and crystal structure of tetrahydro(decacarbonyl)-1,2-ethanediylbis(diphenylphosphine)tetraruthenium. Evidence for an edge-terminal-edge hydride scrambling pathway
3. Crystallographic studies on ruthenium carbonyl hydrides. 3. Molecular geometry of tetra-.mu.-hydrido-[bis-1,2-(diphenylphosphino)ethane]decacarbonyltetraruthenium, including the direct location and refined positions of all four bridging hydride ligands
4. Interaction of dodecacarbonyltetra-.mu.-hydridotetraruthenium with diphosphines in the presence of trimethylamine N-oxide. X-ray crystal structure analyses of (.mu.-H)4Ru4(CO)10(.mu.-{Ph2P(CH2)nPPh2}) (n = 1, 3, 4), (.mu.-H)4Ru4(CO)10(.mu.-{Ph2PCH2CH(CH3)PPh2}), and (.mu.-H)4Ru4(CO)10({Ph2PCH2CH(CH3)PPh2})
5. Chain length effects on the coordination mode of bidentate phosphines in Ru5C(CO)13[PPh2(CH2)nPPh2]: Coordination to non-adjacent metal atoms
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1. Chiral diphosphine derivatives of alkylidyne tricobalt carbonyl clusters – A comparative study of different cobalt carbonyl (pre)catalysts for (asymmetric) intermolecular Pauson–Khand reactions;Polyhedron;2016-01
2. Experimental and Computational Studies of the Isomerization Reactions of Bidentate Phosphine Ligands in Triosmium Clusters: Kinetics of the Rearrangements from Bridged to Chelated Isomers and X-ray Structures of the Clusters Os3(CO)10(dppbz), 1,1-Os3(CO)10(dppbzF4), HOs3(CO)9[μ-1,2-PhP(C6H4-η1)C6H4PPh2], and HOs3(CO)9[μ-1,2-PhP(C6H4-η1)C6F4PPh2];Organometallics;2011-02-22
3. Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os3(CO)10(dppm) to HOs3(CO)8[μ-PhP(C6H4-μ2,η1)CH2PPh2]: Experimental and DFT Evidence for the Participation of Agostic C−H and π-Aryl Intermediates at an Intact Triosmium Cluster;Organometallics;2010-09-01
4. Diphosphine Substitution and Carbyne Ligand Transfer in the Reaction of 2,3-Bis(diphenylphosphino)maleic Anhydride (bma) with the Methylidyne-capped Clusters HCCo2MCp(CO)8 (where M=Mo, W): Synthesis and X-ray Diffraction Structures of the Vinylidene-bridged Clusters Co2MCp(CO)6[μ–C=C(H)CH2C(PPh2)C(PPh2)C(O)OC(O)];Journal of Chemical Crystallography;2008-04-04
5. Slow Migration of a Phosphorus Ligand between Two Metal Centers;Angewandte Chemie International Edition;2007-10-01
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