Diphosphine Substitution and Carbyne Ligand Transfer in the Reaction of 2,3-Bis(diphenylphosphino)maleic Anhydride (bma) with the Methylidyne-capped Clusters HCCo2MCp(CO)8 (where M=Mo, W): Synthesis and X-ray Diffraction Structures of the Vinylidene-bridged Clusters Co2MCp(CO)6[μ–C=C(H)CH2C(PPh2)C(PPh2)C(O)OC(O)]-Reference-Cited by-同舟云学术

Diphosphine Substitution and Carbyne Ligand Transfer in the Reaction of 2,3-Bis(diphenylphosphino)maleic Anhydride (bma) with the Methylidyne-capped Clusters HCCo2MCp(CO)8 (where M=Mo, W): Synthesis and X-ray Diffraction Structures of the Vinylidene-bridged Clusters Co2MCp(CO)6[μ–C=C(H)CH2C(PPh2)C(PPh2)C(O)OC(O)]

Published:2008-04-04 Issue:6 Volume:38 Page:437-445
ISSN:1074-1542
Container-title:Journal of Chemical Crystallography
language:en
Short-container-title:J Chem Crystallogr

Author:

Zhang Weiqiang,Watson William H.,Richmond Michael G.

Publisher

Springer Science and Business Media LLC

Subject

Condensed Matter Physics,General Chemistry

Link

http://link.springer.com/content/pdf/10.1007/s10870-008-9339-5.pdf

Reference50 articles.

1. Yang K, Smith JM, Bott SG, Richmond MG (1993) Organometallics 12:4779

2. For a report on the synthesis and reactivity of PhCCo3(CO)7(bpcd), see: Bott SG, Shen H, Richmond MG (2001) Struct Chem 12:225

3. For the first report involving the bridge-to-chelate isomerization of a diphosphine ligand at a metal cluster and the subsequent kinetics investigation, see: (a) Churchill MR, Lashewycz RA, Shapley JR, Richter SI (1980) Inorg Chem 19:1277

4. (b) Kandala S, Richmond MG (2006) Inorg Chem 45:5976

5. For other documented phosphine ligand isomerizations about a metal cluster, see: (a) Evans J, Gracey BP, Gray LR, Webster M (1982) J Organomet Chem 240:61

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1. Heterometallic Derivatives of the Unsaturated Methyl-Bridged Complex [Mo2(η5-C5H5)2(μ-CH3)(μ-PCy2)(CO)2]. Photochemical Generation of Methylidyne-Bridged Clusters;Organometallics;2010-01-15

2. Spectroscopic and X-ray Diffraction Data on Three Novel Trimetallic Clusters from Thermally Promoted Ligand Substitution in the Tetrahedrane Clusters MeCCo2MoCp(CO)8 and PhCCo2Mo(η5-C5H4CHO)(CO)8;Journal of Chemical Crystallography;2009-05-05