Using Incoming Nucleophile Primary Hydrogen−Deuterium Kinetic Isotope Effects To Model the SN2 Transition State
Author:
Affiliation:
1. Contribution from the Department of Chemistry and Biochemistry, Laurentian University, Sudbury, Ontario, Canada P3E 2C6
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja000441i
Reference69 articles.
1. Isotope effects in nucleophilic substitution reactions XI. The effect of ion-pairing, substituents, and the solvent on SN2 transition states
2. Using 11C/14C Incoming Group and Secondary α-Deuterium KIEs To Determine How a Change in Leaving Group Alters the Structure of the Transition State of the SN2 Reactions between m-Chlorobenzyl para-Substituted Benzenesulfonates and Cyanide Ion
3. Isotope effects in nucleophilic substitution reactions. IV. The effect of changing a substituent at the α carbon on the structure of SN2 transition states
4. Isotope effects in nucleophilic substitution reactions. III. The effect of changing the leaving group on transition state structure in SN2 reactions
5. Sulfur isotope effects in substitution reactions of trimethylsulfonium ion
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