Sulfate-Incarcerating Nanojars: Solution and Solid-State Studies, Sulfate Extraction from Water, and Anion Exchange with Carbonate
Author:
Affiliation:
1. Department of Chemistry, Western Michigan University, Kalamazoo, Michigan 49008, United States
Funder
Division of Chemistry
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.6b01909
Reference40 articles.
1. Anion Encapsulation by Neutral Supramolecular Assemblies of Cyclic CuII Complexes: A Series of Five Polymerization Isomers,[{cis-CuII(μ-OH)(μ-pz)}n],n=6, 8, 9, 12, and 14
2. Selective total encapsulation of the sulfate anion by neutral nano-jars
3. Incarceration of one or two phosphate or arsenate species within nanojars, capped nanojars and nanohelicages: helical chirality from two closely-spaced, head-to-head PO43−or AsO43−ions
4. Survival of the Fittest Nanojar: Stepwise Breakdown of Polydisperse Cu 27 −Cu 31 Nanojar Mixtures into Monodisperse Cu 27 (CO 3 ) and Cu 31 (SO 4 ) Nanojars
5. Tuning the structure and solubility of nanojars by peripheral ligand substitution, leading to unprecedented liquid–liquid extraction of the carbonate ion from water into aliphatic solvents
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