Tuning the structure and solubility of nanojars by peripheral ligand substitution, leading to unprecedented liquid–liquid extraction of the carbonate ion from water into aliphatic solvents-Reference-Cited by-同舟云学术

Tuning the structure and solubility of nanojars by peripheral ligand substitution, leading to unprecedented liquid–liquid extraction of the carbonate ion from water into aliphatic solvents

Published:2016 Issue:20 Volume:45 Page:8327-8339
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ahmed Basil M.¹²³⁴,Calco Brice¹²³⁴,Mezei Gellert¹²³⁴

Affiliation:

1. Department of Chemistry

2. Western Michigan University

3. Kalamazoo

4. USA

Abstract

Carbonate, an anion with large hydration energy, is extracted from water by solvent extraction for the first time, using functionalized nanojars.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00847J

Reference51 articles.

1. Selective total encapsulation of the sulfate anion by neutral nano-jars

2. Incarceration of one or two phosphate or arsenate species within nanojars, capped nanojars and nanohelicages: helical chirality from two closely-spaced, head-to-head PO43−or AsO43−ions

3. Survival of the Fittest Nanojar: Stepwise Breakdown of Polydisperse Cu 27 −Cu 31 Nanojar Mixtures into Monodisperse Cu 27 (CO 3 ) and Cu 31 (SO 4 ) Nanojars

4. Sulfate-binding protein dislikes protonated oxyacids

5. The molecular basis of phosphate discrimination in arsenate-rich environments

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