Molecular and Electronic Structure, and Hydrolytic Reactivity of a Samarium(II) Crown Ether Complex
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, United States
2. Relativistic Molecular Physics Group, Universidad Andres Bello, Replubica 275, Santiago, Chile
Funder
Basic Energy Sciences
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.8b03566
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2. Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2
3. Displacement of a cyclopentadienyl ligand by a crown ether from a lanthanocene(ii) [LnCp′′2]; crystal structures of the first cationic lanthanoid(ii) complexes, [SmCp′′([18]-crown-6)][SmCp′′3]·0.5C6H6 and [YbCp′′([18]-crown-6)][Cp′′]·3C6H6 [Cp′′ = η5-C5H3(SiMe3)2-1,3]
4. Oxidatively Stable, Aqueous Europium(II) Complexes through Steric and Electronic Manipulation of Cryptand Coordination Chemistry
5. Lanthanide(II) Complexes Supported by N,O-Donor Tripodal Ligands: Synthesis, Structure, and Ligand-Dependent Redox Behavior
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