Eightfold Electrophilic Methylation of Octacyanotungstate [W(CN)8]4–/3–: Preparation of Homoleptic, Eight-Coordinate Methyl Isocyanide Complexes [W(CNMe)8]4+/5+
Author:
Affiliation:
1. Freie Universität Berlin, Institut für Chemie und Biochemie−Anorganische Chemie Fabeckstraße 34-36, 14195 Berlin, Germany
Funder
Deutsche Forschungsgemeinschaft
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c00326
Reference72 articles.
1. Syntheses and Structural Characterizations of the First 16-, 17-, and 18-Electron Homoleptic Isocyanide Complexes of Vanadium: Hexakis(2,6-dimethyl- phenyl isocyanide)vanadium(I, 0, −I)1
2. First Homoleptic Isocyanides of Niobium and Tantalum1
3. Homoleptic Isocyanidemetalates of 4d- and 5d-Transition Metals: [Nb(CNXyl)6]-, [Ta(CNXyl)6]-, and Derivatives Thereof1
4. [Fe(CNXyl)4]2−: An Isolable and Structurally Characterized Homoleptic Isocyanidemetalate Dianion
5. Synthesis and Structural Characterization of [Co{CN(2,6-C6H3Me2)}4]-, the First Transition Metal Isonitrilate
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