Towards clustered carbonyl cations [M3(CO)14]2+ (M = Ru, Os): the need for innocent deelectronation-Reference-Cited by-同舟云学术

Towards clustered carbonyl cations [M₃(CO)₁₄]²⁺ (M = Ru, Os): the need for innocent deelectronation

Published:2022 Issue:32 Volume:13 Page:9147-9158
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sellin Malte¹^ORCID,Friedmann Christian¹^ORCID,Mayländer Maximilian²,Richert Sabine²^ORCID,Krossing Ingo¹^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany

2. Institut für Physikalische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany

Abstract

Trimeric M3(CO)12 (M = Ru, Os) reacts with typical inorganic oxidants to unwanted side products. Yet, the 9,10-dichlorooctafluoroanthracene radical cation deelectronates these under CO pressure to give the first homotrimetallic [M3(CO)14]2+ salts.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02358J

Reference93 articles.

1. The chemistry of transition-metal carbonyls: synthesis and reactivity

2. A. J.Lupinetti , S. H.Strauss and G.Frenking , in Progress in Inorganic Chemistry , 2001 , pp. 1–112

3. Metal–CO Bonding in Mononuclear Transition Metal Carbonyl Complexes

4. Metal carbonyl cations: generation, characterization and catalytic application

5. Cationic Iridium(III) Carbonyl Complexes:[Ir(CO)6]3+ and[Ir(CO)5Cl]2+

Cited by 15 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Pushing redox potentials to highly positive values using inert fluorobenzenes and weakly coordinating anions;Nature Communications;2024-08-07

2. Utilizing the Perfluoronaphthalene Radical Cation as a Selective Deelectronator to Access a Variety of Strongly Oxidizing Reactive Cations;Angewandte Chemie International Edition;2024-07-24

3. Nutzung des Perfluornaphthalin‐Radikalkations als selektiver Deelektronierer zur Erzeugung einer Vielzahl stark oxidierender reaktiver Kationen;Angewandte Chemie;2024-07-24

4. Manganese(III) Nitrate Complexes as Bench-Stable Powerful Oxidants;Journal of the American Chemical Society;2024-04-19

5. From the Iron Pentacarbonyl Cation to Heteroleptic η⁶‐arene Carbonyls and bis‐η⁶‐arene Cations;Chemistry – A European Journal;2024-02-22