Density Functional Theory Analysis of the Importance of Coordination Geometry for 5f36d1 versus 5f4 Electron Configurations in U(II) Complexes
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States
Funder
Division of Chemistry
Basic Energy Sciences
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c02161
Reference57 articles.
1. Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C5H4SiMe3)3U]
2. Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported by δ Backbonding
3. Expanding the Chemistry of Molecular U2+Complexes: Synthesis, Characterization, and Reactivity of the {[C5H3(SiMe3)2]3U}−Anion
4. Isolation of U(ii) compounds using strong donor ligands, C5Me4H and N(SiMe3)2, including a three-coordinate U(ii) complex
5. Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs
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