Tin(II)–Nitrene Radical Complexes Formed by Electron Transfer from Redox-Active Ligand to Organic Azides and Their Reactivity in C(sp3)

Tin(II)–Nitrene Radical Complexes Formed by Electron Transfer from Redox-Active Ligand to Organic Azides and Their Reactivity in C(sp3)–H Activation

Published:2021-11-15 Issue:24 Volume:60 Page:18603-18607
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Sugimoto Hideki¹^ORCID,Yano Mayuka¹,Sato Kazunobu²^ORCID,Miyanishi Mayuko³,Sugisaki Kenji²^ORCID,Shiota Yoshihito³^ORCID,Kaga Akira¹,Yoshizawa Kazunari³^ORCID,Itoh Shinobu¹^ORCID

Affiliation:

1. Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

2. Department of Chemistry, Graduate School of Science Osaka City University, 3-3-138 Sumiyoshi, Osaka, Osaka 558-8585, Japan

3. Institute for Materials Chemistry and Engineering and International Research Center for Molecular System, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

Funder

Core Research for Evolutional Science and Technology

Japan Society for the Promotion of Science

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c02806

Reference38 articles.

1. New amination strategies based on nitrogen-centered radical chemistry

2. Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications