Reverse Catalase Reaction: Dioxygen Activation via Two-Electron Transfer from Hydroxide to Dioxygen Mediated By a Manganese(III) Salen Complex
Author:
Affiliation:
1. Institute for Molecular Science, National Institutes of Natural Sciences, Myodaiji, Okazaki, Aichi 444-8787, Japan
Funder
Naito Foundation
Japan Society for the Promotion of Science
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5b01025
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1. Efficient C–H bond activations via O2cleavage by a dianionic cobalt(ii) complex
2. The Direct Oxidative Addition of O2 to a Mononuclear Cr(I) Complex Is Spin Forbidden
3. Characterization of Metastable Intermediates Formed in the Reaction between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)–Peroxo Species
4. “Criss-Crossed” Dinucleating Behavior of an N4 Schiff Base Ligand: Formation of a μ-OH,μ-O2 Dicobalt(III) Core via O2 Activation
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