Characterization of Metastable Intermediates Formed in the Reaction between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)

Characterization of Metastable Intermediates Formed in the Reaction between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)–Peroxo Species

Published:2013-04-03 Issue:15 Volume:135 Page:5631-5640
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Coggins Michael K.¹,Sun Xianru²,Kwak Yeonju³,Solomon Edward I.³,Rybak-Akimova Elena²,Kovacs Julie A.¹

Affiliation:

1. Department of Chemistry, University of Washington, Campus Box 351700 Seattle, Washington 98195-1700, United States

2. Department of Chemistry, Tufts University, 62 Talbot Avenue, Medford, Massachusetts 02155, United States

3. Department of Chemistry, Stanford University, Stanford, California 94305, United States

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja311166u

Reference94 articles.

1. Dioxygen Activation in Soluble Methane Monooxygenase

2. Crystal Structures of Fe 2+ Dioxygenase Superoxo, Alkylperoxo, and Bound Product Intermediates

3. Reactions of Late Transition Metal Complexes with Molecular Oxygen

4. Mn-promoted Aerobic Oxidative C–C Bond Cleavage of Aldehydes with Dioxygen Activation: A Simple Synthetic Approach to Formamides

5. Dioxygen-Coupled Oxidative Amination of Styrene

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