Interstitial Bismuth Atoms in Icosahedral Rhodium Cages: Syntheses, Characterizations, and Molecular Structures of the [Bi@Rh12(CO)27]3–, [(Bi@Rh12(CO)26)2Bi]5–, [Bi@Rh14(CO)27Bi2]3–, and [Bi@Rh17(CO)33Bi2]4– Carbonyl Clusters
Author:
Affiliation:
1. Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Viale del Risorgimento, 4, 40136 Bologna, Italy
Funder
Universit? di Bologna
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.7b00409
Reference49 articles.
1. Metal Clusters in Chemistry
2. [Zn9Bi11]5−: A Ligand-Free Intermetalloid Cluster
3. New High-Nuclearity Carbonyl and Carbonyl-Substituted Rhodium Clusters and Their Relationships with Polyicosahedral Carbonyl-Substituted Palladium- and Gold-Thiolates
4. Synthesis and x-ray structural characterization of the [Rh22(.mu.3-CO)7(.mu.-CO)18(CO)12]4- anion, containing a large close-packed cluster with an ABAC sequence of compact layers
5. Metal–metal and metal–ligand bond strengths in metal carbonyl clusters
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