Highly Stereoselective Photocyclodimerization of α-Cyclodextrin-Appended Anthracene Mediated by γ-Cyclodextrin and Cucurbit[8]uril: A Dramatic Steric Effect Operating Outside the Binding Site
Author:
Affiliation:
1. Department of Applied Chemistry, Osaka University, Suita 565-0871, Japan, and Center for Smart Supramolecules and Department of Chemistry, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja8032923
Reference29 articles.
1. Goodness of Fit in Complexes between Substrates and Ribonuclease Mimics: Effects on Binding, Catalytic Rate Constants, and Regiochemistry
2. Acceleration of a Diels–Alder reaction by a self-assembled molecular capsule
3. Diels-Alder in Aqueous Molecular Hosts: Unusual Regioselectivity and Efficient Catalysis
4. Acid Catalysis in Basic Solution: A Supramolecular Host Promotes Orthoformate Hydrolysis
5. A Hydrophobic Nanocapsule Controls the Photophysics of Aromatic Molecules by Suppressing Their Favored Solution Pathways
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