Dioxygen Reduction to Hydrogen Peroxide by a Molecular Mn Complex: Mechanistic Divergence between Homogeneous and Heterogeneous Reductants
Author:
Affiliation:
1. Department of Chemistry, University of Virginia, PO Box 400319, Charlottesville, Virginia 22904-4319, United States
Funder
College and Graduate School of Arts and Sciences
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.8b13373
Reference56 articles.
1. Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective
2. Dioxygen Activation and Catalytic Reduction to Hydrogen Peroxide by a Thiolate-Bridged Dimanganese(II) Complex with a Pendant Thiol
3. Characterization of Metastable Intermediates Formed in the Reaction between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)–Peroxo Species
4. Characterization and Dioxygen Reactivity of a New Series of Coordinatively Unsaturated Thiolate-Ligated Manganese(II) Complexes
5. Dioxygen Activation by a Manganese Complex Containing a Schiff Base: Selective Oxidation of an Imino to an Amido Group within the Salophen Ligand and Formation of a Hydroxy-Bridged MnIII-Polymer
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