Formation of a Reactive, Alkyl Thiolate-Ligated FeIII-Superoxo Intermediate Derived from Dioxygen
Author:
Affiliation:
1. Department of Chemistry, University of Washington, Campus Box 351700, Seattle, Washington 98195, United States
Funder
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.8b12670
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1. The reaction cycle of isopenicillin N synthase observed by X-ray diffraction
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4. VTVH-MCD and DFT Studies of Thiolate Bonding to {FeNO}7/{FeO2}8 Complexes of Isopenicillin N Synthase: Substrate Determination of Oxidase versus Oxygenase Activity in Nonheme Fe Enzymes
5. An iron–oxygen intermediate formed during the catalytic cycle of cysteine dioxygenase
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