Kinetics of the Reactions of [p-Nitrophenoxy(phenyl)carbene]pentacarbonylchromium(0) with Aryloxide Ions, Hydroxide Ion, and Water in Aqueous Acetonitrile. Concerted or Stepwise?
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064, and Departamento de Química Orgánica, Universidad Nacional de Córdoba, 5000 Córdoba, Argentina
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo062138r
Reference72 articles.
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2. Physical Organic Chemistry of Transition Metal Carbene Complexes. 7.1 Kinetics of Hydrolysis of (CO)5MC(OR)Ph (M = Cr, W; R = Me, Et) and (CO)5Cr(OMe)CHCHPh in Aqueous Acetonitrile
3. Physical Organic Chemistry of Transition Metal Carbene Complexes. 21.1 Kinetics and Mechanism of Hydrolysis of (CO)5MC(SR)Ar (M = Cr and W; R = CH3 and CH3CH2CH2; Ar = C6H5 and 3-ClC6H4) in Aqueous Acetonitrile. Important Differences Relative to Complexes with Alkoxy Leaving Groups
4. Hydrolysis of Fischer Carbene Complexes. Steric Effects of the π-Donor Group
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