Protonation of Rhenium Alkyne Complexes Produces η3-Allyl Rhenium Complexes via Observable 1-Metallacyclopropene Intermediates
Author:
Affiliation:
1. Contribution from the Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9815374
Reference55 articles.
1. Reaction of C5Me5(CO)2Re(HCCCH3)with Ph3C+PF6− produces the η3-allyl complex C5Me5(CO) 2 Re[η3-Ph2CC(Ph)CHCH3]+PF6−
2. Synthesis of η3-Propargyl Rhenium Complexes
3. Basic metals. Part 61. Synthesis of [(C5H5)Rh(.eta.3-1-MeC3H4)[P(CHMe2)3]PF6 from (C5H5)Rh(MeC.tplbond.CMe)[P(CHMe2)3]. The mechanism of conversion of an alkyne into an allyl ligand via an allene intermediate
4. Reactions of co-ordinated ligands. Part 27. Formation of η3-allyl and σ-vinyl complexes by nucleophilic attack on cationic molybdenum monoacetylene complexes. Molecular structures of [Mo(CO)(PEt3)(η3-anti-1-MeC3H4)(η5-C9H7)] and [Mo{P(OMe)3}3{σ-(E)-CHCHBut}(η-C5H5)]
5. Reactions of co-ordinated ligands. Part 33. Mononuclear η2-vinyl complexes: synthesis, structure, and reactivity
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