Ambimodal Bispericyclic [6 + 4]/[4 + 6] Transition State Competes with Diradical Pathways in the Cycloheptatriene Dimerization: Dynamics and Experimental Characterization of Thermal Dimers-Reference-Cited by-同舟云学术

Ambimodal Bispericyclic [6 + 4]/[4 + 6] Transition State Competes with Diradical Pathways in the Cycloheptatriene Dimerization: Dynamics and Experimental Characterization of Thermal Dimers

Published:2022-11-28 Issue:48 Volume:144 Page:22251-22261
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Zhou Qingyang¹,Thøgersen Mathias K.²,Rezayee Nomaan M.²^ORCID,Jørgensen Karl Anker²^ORCID,Houk K. N.³^ORCID

Affiliation:

1. The College of Chemistry, Nankai University, Tianjin 300071, China

2. Department of Chemistry, Aarhus University, Langelandsgade 140, Aarhus C DK-8000, Denmark

3. Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, United States

Funder

Division of Chemistry

Aarhus Universitet

Nankai University

Villum Fonden

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.2c10407

Reference57 articles.

1. An Unexpected Bispericyclic Transition Structure Leading to 4+2 and 2+4 Cycloadducts in the Endo Dimerization of Cyclopentadiene

2. Diels–Alder Reactions of Allene with Benzene and Butadiene: Concerted, Stepwise, and Ambimodal Transition States

3. Post-transition state bifurcations gain momentum – current state of the field

4. Expanding the Frontiers of Higher-Order Cycloadditions

5. Cycloadditions of Cyclopentadiene and Cycloheptatriene with Tropones: All Endo-[6+4] Cycloadditions Are Ambimodal

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