Reactivity of Heterobimetallic Alkoxysilyl and Siloxy Complexes in the Catalytic Dehydrogenative Coupling of Tin Hydrides
Author:
Affiliation:
1. Laboratoire de Chimie de Coordination, Associé au CNRS (UMR 7513), Université Louis Pasteur, 4 rue Blaise Pascal, F-67070 Strasbourg Cedex, France
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om970353f
Reference55 articles.
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2. Synthesis and structure of bimetallic allyl, alkoxysilyl complexes [Fe{Si(OMe)3}(CO)3(.mu.-dppm)M(.eta.3-2-RC3H4)] M = Pd, Pt; R = H, Me) and of [Fe{.mu.-Si(OMe)2(OMe)}(CO)3(.mu.-dppm)Pd(SnPh3)], a Sn-Pd-Fe-Si chain complex with a .mu.2-.eta.2-SiO bridge
3. Synthesis and reactivity of phosphine-substituted hydrido silyl complexes mer-[FeH(SiR3)(CO)3{Ph2P(CH2)nPPh2}](n= 1 or 4), mer-[FeH{Si(OMe)3}(CO)3(PPh2H)] and mer-[FeH{Si(OMe)3}(CO)3{Ph2PCH2C(O)Ph}]. Synthesis of bimetallic complexes and crystal structure of mer-[(Ph3P)Cu(µ-dppm)Fe{Si(OMe)3}(CO)3]
4. Synthesis and reactivity of bimetallic alkoxysilyl complexes. Crystal structure of [cyclic][Fe(CO)3{.mu.-Si(OMe)2(OMe)}(.mu.-dppm)Rh(CO)] (dppm = Ph2PCH2PPh2): a complex with a .mu.2-.eta.2-SiO bridge between iron and rhodium
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