Reactivity of Diphenylphosphino Enolato Ligands in Ruthenium(II) Complexes and Related Processes Involving Easy Cleavage of a Phosphorus−Carbon Bond in Functionalized Phosphine Ligands
Author:
Affiliation:
1. Laboratoire de Chimie de Coordination Organique, URA-CNRS 415, Campus de Beaulieu, Université de Rennes, 35042 Rennes Cédex, France
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9600607
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5. Hydrido heterobimetallic bis(diphenylphosphino)methane-bridged ruthenium-rhodium complexes. Activation of a phosphorus-carbon bond of bis(diphenylphosphino)methane to give a heterobimetallic ruthenium-rhodium complex containing a trans-hydridophenylruthenium moiety. X-ray crystal structure of RuRhH(C6H5)(C8H12)[C6H5PCH2P(C6H5)2][(C6H5)2PCH2P(C6H5)2].cntdot.0.5C6H5CH3
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