Blue‐Light Driven Iron‐Catalyzed Oxy‐phosphinylation of Activated Alkenes for β‐Ketophosphine Oxide Synthesis-Reference-Cited by-同舟云学术

Blue‐Light Driven Iron‐Catalyzed Oxy‐phosphinylation of Activated Alkenes for β‐Ketophosphine Oxide Synthesis

Published:2023-10-26 Issue:69 Volume:29 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Yuan Yumeng¹²,Huang Qiufeng²,Darcel Christophe¹^ORCID

Affiliation:

1. CNRS ISCR UMR 6226 Univ. Rennes F 35000 Rennes France

2. College of Chemistry & Materials Science Fujian Normal University 350007 Fuzhou P. R. China

Abstract

AbstractWe have developed an original blue‐light mediated iron‐catalyzed oxy‐phosphinylation of activated alkenes by secondary phosphine oxides under air at room temperature. Various β‐ketophosphine oxides were then obtained in 43–97 % isolated yields. Control experiments revealed that radical process is involved in the mechanism.

Funder

Université de Rennes 1

Centre National de la Recherche Scientifique

China Scholarship Council

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

Reference89 articles.

2. The Wittig olefination reaction and modifications involving phosphoryl-stabilized carbanions. Stereochemistry, mechanism, and selected synthetic aspects

3. Recent topics of the natural product synthesis by Horner–Wadsworth–Emmons reaction

4. For selected examples see:

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