Glycosidic Bond Formation in Aqueous Solution: On the Oxocarbenium Intermediate
Author:
Affiliation:
1. Contribution from Lehrstuhl für Theoretische Chemie, Ruhr-Universität Bochum, 44780 Bochum, Germany
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja035600n
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1. Complete kinetic isotope effect description of transition states for acid-catalyzed hydrolyses of methyl .alpha.- and .beta.-glucopyranosides
2. Hydrolysis of (2-Deoxy-α-d-Glucopyranosyl)pyridinium Salts: The 2-Deoxyglucosyl Oxocarbenium Is Not Solvent-Equilibrated in Water
3. Hydrolysis of (2-Deoxy-.beta.-D-glucopyranosyl)pyridinium Salts
4. The Role of Sugar Substituents in Glycoside Hydrolysis
5. A Kinetic Isotope Effect Study on the Hydrolysis Reactions of Methyl Xylopyranosides and Methyl 5-Thioxylopyranosides: Oxygen versus Sulfur Stabilization of Carbenium Ions
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