Elucidation of a Sc(I) Complex by DFT Calculations and Reactivity Studies

Author:

Neculai Ana-Mirela1,Cummins Christopher C.1,Neculai Dante1,Roesky Herbert W.1,Bunkòczi Gàbor1,Walfort Bernhardt1,Stalke Dietmar1

Affiliation:

1. Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany, Institut für Anorganische Chemie, Am Hubland, D-97074 Würzburg, Germany, and Department of Chemistry Room 2-227, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139-4307

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference42 articles.

1. (a) Huheey, J. E.; Keiter, E. A.; Keiter, R. L.Inorganic Chemistry: Principles of Structure and Reactivity, 4th ed.; Harper Collins College Publishers:  New York, 1993; pp 509−602.

2. (b) Cotton, F. A.; Wilkinson, E.; Murillo, C. A.; Bochmann, M.Advanced Inorganic Chemistry, 6th ed.; John Wiley & Sons:  New York, 1999; p 1127.

3. The First Example of a Crystalline Subvalent Organolanthanum Complex:  [K([18]crown-6)- (η2-C6H6)2][(LaCptt2)2(μ-η6:η6-C6H6)]•2C6H6 (Cptt = η5-C5H3But2-1,3)

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