Effect of Ancillary Ligation on the Relative Bond Disruption Enthalpies of Ru−H and Ru−Cl Bonds in Cp(PR3)2RuX (PR3 = PMe3, PMe2Ph, PMePh2, PPh3; X = H, Cl)

Author:

Freeman Samuel T. N.,Lemke Frederick R.,Haar Christopher M.,Nolan Steven P.,Petersen Jeffrey L.1

Affiliation:

1. Department of Chemistry, West Virginia University, Morgantown, West Virginia 26506

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference32 articles.

1. Transition Metal Hydrides; Dedieu, A., Ed.; VCH Publishers:  New York, 1992; p 399.

2. Parshall, G. W.; Ittel, S. D.Homogeneous Catalysis,2nd ed.; John Wiley & Sons:  New York, 1992; p 342.

3. Ruthenium Silyl Complexes from the Reaction of Chlorosilanes with an Amphoteric Ruthenium Hydride. Evidence for an Agostic Ru-H-Si Intermediate

4. Ruthenium Silyl Complexes Containing the Cp(PMe3)2Ru Moiety:  Preparation, Substituent Effects, and Silylene Character in the Ru−Si Bond

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