The First Crystalline Alkali Metal Salt of a Benzenoid Radical Anion without a Stabilizing Substituent and of a Related Dimer: X-ray Structures of the Toluene Radical Anion and of the Benzene Radical Anion Dimer Potassium-Crown Ether Salts
Author:
Affiliation:
1. The Chemical Laboratory, University of Sussex Brighton, BN1 9QJ, United Kingdom
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja005580e
Reference29 articles.
1. The First Example of a Crystalline Subvalent Organolanthanum Complex: [K([18]crown-6)- (η2-C6H6)2][(LaCptt2)2(μ-η6:η6-C6H6)]•2C6H6 (Cptt = η5-C5H3But2-1,3)
2. Synthesis and Characterization of Organolanthanidocene(III) (Ln = La, Ce, Pr, Nd) Complexes Containing the 1,4-Cyclohexa-2,5-dienyl Ligand (Benzene 1,4-Dianion): Structures of [K([18]-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)] [Cp‘ ‘ = η5-C5H3(SiMe3)2-1,3; Ln = La, Ce, Nd]
3. Stimulated Raman scattering from molecular hydrogen gas for fast heating in laser-temperature-jump chemical relaxation experiments
4. Bis(trimethylphosphoranylidene)methane, (CH3)3PCP(CH3)3
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