Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes-Reference-Cited by-同舟云学术

Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes

Published:2004-03-25 Issue:15 Volume:126 Page:4859-4864
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Gais Hans-Joachim¹,Reddy Leleti R.¹,Babu Gadamsetti S.¹,Raabe Gerhard¹

Affiliation:

1. Contribution from the Institut für Organische Chemie der Rheinisch-Westfälischen Technischen Hochschule (RWTH) Aachen, Prof.-Pirlet-Strasse 1, D-52056 Aachen, Germany

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja030501v

Reference86 articles.

1. Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides

2. A New Synthesis of 5-Trimethylsilyl-2,3-dihydrofurans from β-Trimethylsiloxyketones Utilizing Trimethylsilyldiazomethane

3. Intramolecular insertion reaction of alkylidenecarbenes into oxygen-silicon bonds

4. Alkynyliodonium Salts in Organic Synthesis. Dihydrofuran Formation via a Formal Stevens Shift of a Carbon Substituent within a Disubstituted-Carbon Oxonium Ylide

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