Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides-Reference-Cited by-同舟云学术

Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides

Published:2002-08-08 Issue:35 Volume:124 Page:10427-10434
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Reddy Leleti Rajender¹,Gais Hans-Joachim¹,Woo Chang-Wan¹,Raabe Gerhard¹

Affiliation:

1. Contribution from the Institut für Organische Chemie der Rheinisch−Westfälischen Technischen Hochschule (RWTH) Aachen, Professor-Pirlet-Strasse 1, D-52056 Aachen, Germany

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja020570u

Reference80 articles.

1. Synthesis of β-Hydroxy Ketones and Vinylsilanes from Homopropargylic Alcohols by Intramolecular Hydrosilation

2. Tandem Intramolecular Alkyne Silylformylation-Allylsilylation: A Case of Remote 1,5-Asymmetric Induction

3. Regiospecific epoxide opening with acetylenic alanes. Improved total synthesis of E and F prostaglandins

4. General approach to prostaglandins via methylenecyclopentanones. Total synthesis of (+-)-prostaglandin F2.alpha.

5. Total synthesis of erythromycins. 3. Stereoselective routes to intermediates corresponding to C(1) to C(9) and C(10) to C(13) fragments of erythronolide B

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